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rearranged product, but especially to the photooxidation products, orthoquinone and orthodiphenoquinone, which are highly yellow colored [48 51]. Initiation of photooxidation of PC by longer wavelengths is generally attributed to UV absorption by the defects and impurities, which are primarily thermal oxidation products. It has been suggested [50] that radical chain photooxidation processes caused by solar radiation may also result from the photo-Fries reactions initiated by the short wavelengths. The hydroperoxide intermediate that forms absorbs longer wavelength UV than the original impurities and photodegrades to a variety of oxidation products. Photoinduced oxidation on the side chains and phenyl rings [52] result in a mixture of highly colored ring oxidation species that are mainly responsible for the yellow color in polycarbonate by this mechanism [49, 50, 53 59]. Charge-transfer complexes of O2 /PC are believed to contribute signi cantly to photooxidation in the early stages [20]. Increase in the rate of photooxidation by hydrolysis becomes important on prolonged exposure [60]. The relative amount of degradation by the photo-Fries mechanism versus the autocatalytic photooxidation process when PC is exposed outdoors will vary with location, season, angle of exposure, and atmospheric conditions since these factors in uence the short-wavelength cutoff of solar radiation. In blends of PC with PP, PC stabilizes PP when it is present at low concentrations ( 10%), but when PC is the major component, PP sensitizes the photooxidation of PC.

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Entities are persisted through methods invoked on the EntityManager instance. Each entity may be in one of four possible states: new, managed, detached, or removed. The entities move between these states depending on the method invoked on the EntityManager instance. A new entity instance is one that has not yet been managed or persisted. A managed entity instance is one that has been persisted and thus is associated with a persistence context. A detached entity instance is one that was previously managed but is not currently associated with a persistence context. A removed entity instance is one that has a persistent identity, is associated with a persistent context, and is to be queued up for removal.

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A title block is a rectangle that includes spaces for the drawing title, company name, drafter name, and so on. It generally comes with a border that bounds your drawing. Many drawings require title blocks. You can insert an existing title block in two ways: When creating a new drawing, choose File New to open the Select Template dialog box. Choose one of the templates that include a title block. For example, ANSI A Named Plot Styles.dwt includes a title block and border that fit on an A-size sheet. The title block and border appear on a layout tab. ( 17 covers layouts.) After you open a drawing, you can insert a drawing of a title block into it. Choose Insert Block. ( 18 covers blocks.) In the Insert dialog box, type the name of the drawing or block, or click Browse to find it. Most of the templates have a corresponding drawing that you can insert. To insert the file or block at 0,0 with no scaling or rotation, uncheck all of the Specify On-Screen check boxes. Check Explode if you expect to edit the inserted title block after it s in your drawing. Click OK. To find the location of the templates and their corresponding drawings, choose Tools Options and click the Files tab. Double-click Template Settings and then double-click Drawing Template File Location. You see the path to the location displayed. (The path is very long!) This folder may be hidden in Windows Explorer. For instructions on displaying hidden folders, go to Windows Help and type hidden folders in the search box.

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